Oxidation Numbers

Definition

Oxidation number, also called oxidation state, is the total number of electrons that an atom either gains or loses in order to form a chemical bond with another atom

Rules

[!rules]
todo rules with groups

Rules

  1. The oxidation number of any uncombined element or element in a diatomic gas is a zero
    • in
  2. The oxidation number of any monatomic ion is equal to its charge
    • in
    • in
  3. In ionic compounds, the sum of the oxidation numbers of the elements in a compound or ion must equal the overall charge
  4. In covalent compounds with no or : treat like an ionic compound. The more electronegative element assumes a charge equal to what it would be in an ionic compound
    • in
    • in

Other Rules

Element Oxidation Number Exceptions
None
In compounds with , peroxides and superoxides
In metal hydrides (-1) or if it's in an ionic compound
Group 1 metals None
Group 2 metals None

Examples

  • What is the oxidation number of ?
    • 0
  • What is the oxidation state of in ?
    • +2
  • What is the oxidation number of in ?
    • +4 since
  • What is the oxidation state of in
    • +6 since
  • What is the oxidation number of carbon in the carbonate ion,
    • +4, since the whole ion has charge -2, and

Exceptions to the rules

todo