Intermolecular Forces

Definition

Intermolecular forces act between molecules or ions and must be overcome during a physical change

These forces are collectively known as Van der Waals forces

Types of Forces

Dipole-Dipole

Definition

The force of 2 dipole molecules

Example

Hydrogen Bonding

Definition

A special case of dipole-dipole bonding that involves a molecule containing H and a very electronegative element (F, O, and N)

Known as a "hydrogen bond", but is actually a very strong dipole-dipole force (10x stronger)

Example

Ion-Dipole

Example

Ion-Induced dipole

Info

An ion is brought close to a non-polar molecule and then electrons from the molecule go to one side of the molecule causing an electron imbalance Molecular Polarity

When the ion is moved away, the polarized non-polar molecule becomes non-polar again

Example

Dipole-Induced dipole

Info

A dipole molecule is brought close to a non-polar molecule and the partially positive or negative side attracts or repels electrons on the non-polar molecule causing an electron imbalance

When the dipole is moved away, the polarized non-polar molecule becomes non-polar again

Example

London Dispersion Forces

Info

Happens when more electrons end up on one atom temporarily and by chance, causing the atom to become a dipole temporarily

Example

LDFs are present in all molecules, but are weak. Force increases as the number of electrons in a molecule increase

---> LDF increases with # of electrons --->